Advanced Organic Chemistry: Reactions And Synthesis

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d) In their development of a peroxisome proliferator-activated receptor-gamma (PPAR) ligand, the researchers reported an X-ray crystal structure of T2384 bound to the PPAR active site. They showed one important anchor in holding T2384 in the active site was a  or aromatic stacking between the A ring and Phe363. Draw the structure of phenylalanine and analyze the electronic nature of these two rings, i.e. are these rings electron rich or electron poor? It is often seen that an electron rich-electron poor.

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b) Why is this reaction a target for cancer treatment? The phosphorylation of the amino .

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